Peer-Reviewed Publications


Arizona State University


28. Hydroboration of Alkynes and Nitriles Using an α-Diimine Cobalt Hydride Catalyst.

Ben-Daat, H.; Rock, C. L.; Flores, M.; Groy, T. L.; Trovitch, R. J.

Chem. Commun. 2017, 53, 7333-7336.



27. Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation.

Mukhopadhyay, T. K.; Rock, C. L.; Hong, M.; Ashley, D. C.; Groy, T. L.; Baik, M.-H.; Trovitch, R. J.

J. Am. Chem. Soc. 2017, 139, 4901–4915.



26. Hydrogen Production from Water using a Bis(imino)pyridine Molybdenum Electrocatalyst.

Pal, R.; Laureanti, J. A.; Groy, T. L.; Jones, A. K.; Trovitch, R. J.

Chem. Commun. 2016, 52, 11555-11558.





25. Reactivity of (Triphos)FeBr2(CO) towards Sodium Borohydrides.

Mukhopadhyay, T. K.; Groy, T. L.; Smythe, N. C.; Gordon, J. C.; Trovitch, R. J.

J. Coord. Chem. 2016, 69, 2083-2046. (Invited for Emerging Leaders Issue).



24. Isolation of a Bis(imino)pyridine Molybdenum(I) Iodide Complex through Controlled Reduction and Interconversion of its Reaction Products.

Pal, R.; Cherry, B. R.; Flores, M.; Groy, T. L.; Trovitch, R. J.

Dalton Trans. 2016, 45, 10024-10033. (Invited for New Talent: Americas Issue).



23. Two-step C-H, C-P Bond Activation at an α-Diimine Iron Dinitrogen Complex.

Ghosh, C.; Groy, T. L.; Bowman, A. C.; Trovitch, R. J.

Chem. Commun. 2016, 52, 4553-4556.

 



22. A Pentacoordinate Mn(II) Precatalyst That Exhibits Notable Aldehyde and Ketone Hydrosilylation Turnover

Frequencies


Ghosh, C.; Mukhopadhyay, T. K.; Flores, M.; Groy, T. L.; Trovitch, R. J.

Inorg. Chem. 2015, 54, 10398-10406.



21. Conversion of Carbon Dioxide to Methanol Using a C-H Activated Bis(imino)pyridine Molybdenum Hydroboration

Catalyst


Pal, R.; Groy, T. L.; Trovitch, R. J.

Inorg. Chem. 2015, 54, 7506-7515.



20. Carbon Dioxide Promoted H+ Reduction using a Bis(imino)pyridine Manganese Electrocatalyst

Mukhopadhyay, T. K.; MacLean, N. L.; Gan, L.; Ashley, D. C.; Groy, T. L.; Baik, M. -H.; Jones, A. K.; Trovitch, R. J.

Inorg. Chem. 2015, 54, 4475-4482.




19. A New Spin on Cyclooctatetraene (COT) Redox-Activity: Low-Spin Fe(I) Complexes that Exhibit Antiferromagnetic

Coupling to a Singly Reduced η4-COT Ligand


Mukhopadhyay, T. K.; Flores, M.; Feller, R. K.; Scott, B. L.; Taylor, R. D.; Paz-Pasternak, M.; Henson, N. J.; Rein, F.

N.; Smythe, N. C.; Trovitch, R. J.; Gordon, J. C.


Organometallics 2014, 33, 7101-7112.




18. Preparation and Hydrosilylation Activity of a Molybdenum Carbonyl Complex That Features a Pentadentate

Bis(imino)pyridine Ligand


Pal, R.; Groy, T. L.; Bowman, A. C.; Trovitch, R. J.

Inorg. Chem. 2014, 53, 9357-9365




17. Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts

Trovitch, R. J.

Synlett 2014, 25, 1638-1642 (Invited Synpacts Article)




16. A Highly Active Manganese Precatalyst for the Hydrosilylation of Ketones and Esters

Mukhopadhyay, T. K.; Flores, M.; Groy, T. L.; Trovitch, R. J.

J. Am. Chem. Soc. 2014, 136, 882-885





15. Importance of Co-donor Field Strength in the Preparation of Tetradentate α-Diimine Nickel Hydrosilylation Catalysts

Porter, T. M.; Hall, G. B.; Groy, T. L.; Trovitch, R. J.

Dalton Trans. 2013, 42, 14689-14692





14. Rational Design of Rhodium Complexes Featuring κ4-N,N,N,N- and κ5-N,N,N,P,P-Bis(imino)pyridine Ligands

Ben-Daat, H.; Hall, G. B.; Groy, T. L.; Trovitch, R. J

Eur. J. Inorg. Chem. 2013, 4430-4442




13. Investigation of Formally Zerovalent Triphos Iron Complexes

Mukhopadhyay, T. K.; Feller, R. K.; Rein, F. N.; Henson, N. J.; Smythe, N. C.; Trovitch, R. J.; Gordon, J. C

Chem. Commun. 2012, 48, 8670-8672

           


Los Alamos National Laboratory


12. Spectroscopic Characterization of Alumina-Supported Bis(allyl)iridium Complexes: Site-isolation, Reactivity, and

Decomposition Studies

Trovitch, R. J.; Guo, N.; Janicke, M. T.; Li, H.; Marshall, C. L.; Miller, J. T.; Sattelberger, A. P.; John, K. D.; Baker, R. T.

Inorg. Chem. 2010, 49, 2247-2258


11. Interplay of Metal-Allyl and Metal-Metal Bonding in Dimolybdenum Allyl Complexes

Trovitch, R. J.; John, K. D.; Martin, R. L.; Obrey, S. J.; Scott, B. L.; Sattelberger, A. P.; Baker, R. T.

Chem. Commun. 2009, 4206-4208


Cornell University


10. Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and

Electronic Structures of [(PDI)2Fe] Derivatives

Wile, B. M.; Trovitch, R. J.; Bart, S. C.; Tondreau, A. M.; Lobkovsky, E.; Milsmann, C.; Bill, E.; Wieghardt, K.; Chirik, P. J.

Inorg. Chem. 2009, 48, 4190-4200


9. Carbon-Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and

Observation of Acyl C-O Bond Cleavage in Esters

Trovitch, R. J.; Lobkovsky, E.; Bouwkamp, M. W.; Chirik, P. J.

Organometallics 2008, 27, 6264-6278


8. Bis(imino)pyridine Iron Alkyls Containing β-Hydrogens: Synthesis, Evaluation of Kinetic Stability, and

Decomposition Pathways Involving Chelate Participation

Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J

J. Am. Chem. Soc. 2008, 130, 11631-11640


7. Functional Group Tolerance and Substrate Scope in Bis(imino)pyridine Iron Catalyzed Alkene Hydrogenation

Trovitch, R. J.; Lobkovsky, E.; Bill, E.; Chirik, P. J.

Organometallics 2008, 27, 1470-1478


6. Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3 and

FeCH2CMe3 Derivatives

Fernández, I.; Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J

Organometallics 2008, 27, 109-118


5. Bis(diisopropylphosphino)pyridine Iron Dicarbonyl, Dihydride and Silyl Hydride Complexes

Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J

Inorg. Chem. 2006, 45, 7252-7260


4. Square Planar Bis(imino)pyridine Iron Halide and Alkyl Complexes

Bouwkamp, M. W.; Bart, S. C.; Hawrelak, E. J.; Trovitch, R. J.; Lobkovsky, E.; Chirik, P. J

Chem. Commun. 2005, 3406-3408


King's College


3. Synthesis, Structure and Magnetic Properties of a Copper Molybdate Hybrid Inorganic/Organic Solid with a Novel

10-Connected Three-Dimensional Network Topology

Montney, M. R.; Thomas, J. G.; Supkowski, R. M.; Trovitch, R. J.; Zubieta, J.; LaDuca, R. L.

Inorg. Chem. Commun. 2009, 12, 534-539


2. A Coordination Polymer with Conformationally Distinct Layers:

Poly[(μ-1,3-di-4-pyridylpropane-κ2N,N’)bis(μ3-thiocyanato-κ3N,S:S)dicopper(I)]

Trovitch, R. J.; Rarig, R. S.; Zubieta, J. A.; LaDuca, R. L.

Acta Cryst. 2007, E63, m339-m341


1. Divalent Nickel and Monovalent Copper Pseudohalide Coordination Polymers Incorporating the Kinked

Organodiimine 4,4’-Dipyridalamine: From a (4,4)-Type Lamellar Motif to an Unprecedented Staircase  Morphology

Knapp, W. R.; Thomas; J. G.; Martin, D. P.; Braverman, M. A.; Trovitch, R. J.; LaDuca, R. L.

Z. Anorg. Allg. Chem. 2007, 633, 575-581.

















Trovitch Laboratory
Physical Science Building, D-318
School of Molecular Sciences
 Arizona State University
Tempe, AZ, 85287
Call: (+1) 480-965-7728
Email: ryan.trovitch@asu.edu

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  TROVITCH RESEARCH GROUP

INORGANIC AND ORGANOMETALLIC CHEMISTRY